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Angew Chem Int Ed Engl. 2009;48(27):5010-3. doi: 10.1002/anie.200901434.

Comparison of cyanide and carbon monoxide as ligands in iron(II) porphyrinates.

Author information

1
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.

Abstract

Spot the difference: The five-coordinate iron(II) cyanoporphyrinates, which are spin-crossover compounds, can be used to synthesize previously unknown six-coordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five- and six-coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes.

PMID:
19492380
PMCID:
PMC2893548
DOI:
10.1002/anie.200901434
[Indexed for MEDLINE]
Free PMC Article

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