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Chemistry. 2009 Jun 22;15(26):6345-8. doi: 10.1002/chem.200901064.

A unified strategy for the stereospecific construction of propionates and acetate-propionates relying on a directed allylic substitution.

Author information

1
Institut für Organische Chemie und Biochemie, Freiburg Institute for Advanced Studies (FRIAS), Albert-Ludwigs-Universität Freiburg i. Brsg. Albertstrasse 21, 79104 Freiburg i. Brsg., Germany.

Abstract

Flexible friends: A new strategy that relies on o-DPPB-directed allylic substitution has been implemented for the flexible and stereospecific construction of major polyketide and isoprenoid structural elements (see scheme; o-DPPB=ortho-diphenylphosphanyl benzoate; PG=protecting group).

PMID:
19479928
DOI:
10.1002/chem.200901064

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