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Inorg Chem. 2009 Jun 1;48(11):4619-21. doi: 10.1021/ic9003627.

Synthetic, structural, and theoretical investigation of guanidinate complexes containing planar Cu(6) cores.

Author information

1
Department of Chemistry, Kent State University, Kent, Ohio 44242-0001, USA. sbunge@kent.edu

Abstract

The addition of diethylcyanamide to a tetrahydrofuran solution of lithium dialkylamide LiN(CH(3))(2) or Li NCH(2)CH(2)CH(2) CH(2), Li(PYR), results in the corresponding lithium 1,1,3,3-tetraalkylguanidinate, Li(TAG). The subsequent metathesis reaction of Li(TAG) with CuCl generates hexanuclear copper(I) complexes with the general formula [Cu(mu-TAG)](6), where TAG = DEDMG (1) and DEPYRG (2).

PMID:
19388654
DOI:
10.1021/ic9003627
[Indexed for MEDLINE]

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