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Chem Soc Rev. 2009 May;38(5):1450-9. doi: 10.1039/b807080f. Epub 2009 Mar 17.

Metal-organic framework materials as catalysts.

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1
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.

Abstract

A critical review of the emerging field of MOF-based catalysis is presented. Discussed are examples of: (a) opportunistic catalysis with metal nodes, (b) designed catalysis with framework nodes, (c) catalysis by homogeneous catalysts incorporated as framework struts, (d) catalysis by MOF-encapsulated molecular species, (e) catalysis by metal-free organic struts or cavity modifiers, and (f) catalysis by MOF-encapsulated clusters (66 references).

PMID:
19384447
DOI:
10.1039/b807080f

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