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Chem Soc Rev. 2009 May;38(5):1353-79. doi: 10.1039/b804757j. Epub 2009 Feb 24.

Magnetic metal-organic frameworks.

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1
Laboratoire de Chimie de Coordination Organique, CNRS-UMR7140, Université de Strasbourg, 4 rue Blaise Pascal, 67000, Strasbourg Cedex, France. kurmoo@chimie.u-strasbg.fr

Abstract

The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the field of magnetic metal-organic frameworks, in particular those containing cobalt(II). We examine the diversity of magnetic exchange interactions between nearest-neighbour moment carriers, covering from dimers to oligomers and discuss their implications in infinite chains, layers and networks, having a variety of topologies. We progress to the different forms of short-range magnetic ordering, giving rise to single-molecule-magnets and single-chain-magnets, to long-range ordering of two- and three-dimensional networks (323 references).

PMID:
19384442
DOI:
10.1039/b804757j
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