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Chem Commun (Camb). 2009 May 7;(17):2371-2. doi: 10.1039/b820402k. Epub 2009 Mar 11.

An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts.

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1
Process Engineering Applied Chemistry and Biotechnology Division Indian Institute of Petroleum, Dehradun, India.

Abstract

The first report on the use of vanadium-based catalysts for oxidative cyanation of tertiary amines with molecular oxygen in the presence of sodium cyanide and acetic acid to afford the corresponding alpha-aminonitriles in good to excellent yields is described.

PMID:
19377689
DOI:
10.1039/b820402k
[Indexed for MEDLINE]
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