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J Am Chem Soc. 2009 May 13;131(18):6368-9. doi: 10.1021/ja901731z.

Interconversion between molecular polyhedra and metal-organic frameworks.

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1
Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012, USA.

Abstract

The construction of a metal-organic framework (MOF) with a pcu-a topology using a preassembled soluble molecular octahedron has been realized experimentally. The resulting MOF can also be reversibly converted to the molecular octahedron. All such conversions are based on axial-ligand substitution reactions on the molecular octahedron.

PMID:
19374418
DOI:
10.1021/ja901731z
[Indexed for MEDLINE]
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