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Chem Commun (Camb). 2009 Feb 7;(5):600-2. doi: 10.1039/b818961g. Epub 2008 Dec 11.

Iron-catalysed Negishi coupling of benzyl halides and phosphates.

Author information

  • 1School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS. r.bedford@bristol.ac.uk

Abstract

Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzyl halides and phosphates.

PMID:
19283304
DOI:
10.1039/b818961g
[PubMed - indexed for MEDLINE]
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