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Phys Rev Lett. 2009 Feb 27;102(8):085703. Epub 2009 Feb 27.

Probing the equilibrium dynamics of colloidal hard spheres above the mode-coupling glass transition.

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1
Laboratoire des Colloïdes, Verres et Nanomatériaux, UMR 5587, Université Montpellier II and CNRS, 34095 Montpellier, France.

Abstract

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades in structural relaxation time, tau(alpha0, including equilibrium measurements above phi(c), the location of the glass transition deduced from fitting our data to mode-coupling theory. Instead of falling out of equilibrium, the system remains ergodic above phi

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