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J Am Chem Soc. 2009 Mar 25;131(11):3796-7. doi: 10.1021/ja8054595.

Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex.

Author information

1
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

Abstract

This communication describes the rational design and synthesis of the remarkably stable Pd(IV) monoaryl fluoride complex (t-Bu-bpy)Pd(IV)(p-FC(6)H(4))(F)(2)(FHF) (t-Bu-bpy = 4,4'-di-tert-butyl-2,2'-bipyridine). This and related complexes undergo Ar-F bond formation in the presence of "F(+)" sources. This work serves as a foundation for the development of Pd(II/IV)-catalyzed coupling reactions to form aryl fluorides.

PMID:
19249867
PMCID:
PMC2713824
DOI:
10.1021/ja8054595
[Indexed for MEDLINE]
Free PMC Article

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