Nanoparticle-supported and magnetically recoverable palladium (Pd) catalyst: a selective and sustainable oxidation protocol with high turnover number

Org Biomol Chem. 2009 Jan 7;7(1):37-40. doi: 10.1039/b817669h. Epub 2008 Nov 13.

Abstract

A magnetic nanoparticle-supported Pd catalyst was readily prepared from inexpensive starting materials and shown to catalyze various oxidation reactions with high turnover number (TON) and excellent selectivity. The ease of recovery using an external magnetic field, high activity, and the intrinsic stability of the catalyst make this protocol economic and sustainable.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Alcohols / chemistry
  • Catalysis
  • Iron / chemistry
  • Magnetics
  • Microscopy, Electron, Transmission
  • Models, Chemical
  • Molecular Conformation
  • Molecular Structure
  • Nanoparticles / chemistry*
  • Nanotechnology / methods*
  • Oxygen / chemistry*
  • Palladium / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • Temperature
  • X-Ray Diffraction

Substances

  • Alcohols
  • Palladium
  • Iron
  • Oxygen