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Opt Lett. 2008 Nov 15;33(22):2620-2.

Laser-induced fluorescence of NCN in low and atmospheric pressure flames.

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1
Applied Molecular Physics, Institute for Molecules and Materials, Radboud University Nijmegen, Nijmegen, The Netherlands. R.Klein-Douwel@science.ru.nl

Abstract

The cyanonitrene radical, NCN, is detected by laser-induced fluorescence in laminar, adiabatic, flat phi=1.3 methane-air flames at 200 hPa and atmospheric pressure. Laser excitation of the A approximately 3Piu(020)-X approximately 3Sigmag-(000) band at 317 nm allows off-resonant fluorescence to be detected at 326 nm. Excitation and dispersed fluorescence spectra are presented, as well as profiles of NCN and CH versus height above burner.

PMID:
19015687
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