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Org Biomol Chem. 2008 Nov 21;6(22):4083-8. doi: 10.1039/b813246a. Epub 2008 Oct 9.

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions.

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1
Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, USA.

Abstract

Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential. This emerging area examines recent developments of palladium-catalyzed difunctionalization reactions, with a focus on mechanistic strategies that allow for functionalization of a common palladium alkyl intermediate.

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