Use of 1-alkyl-3-methylimidazolium hexafluorophosphate room temperature ionic liquids as chelate extraction solvent with 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione

Naoki Hirayama; Mika Deguchi; Hitomi Kawasumi; Takaharu Honjo

doi:10.1016/j.talanta.2004.06.015

Use of 1-alkyl-3-methylimidazolium hexafluorophosphate room temperature ionic liquids as chelate extraction solvent with 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione

Talanta. 2005 Jan 15;65(1):255-60. doi: 10.1016/j.talanta.2004.06.015.

Authors

Naoki Hirayama¹, Mika Deguchi, Hitomi Kawasumi, Takaharu Honjo

Affiliation

¹ Department of Chemistry, Faculty of Science, Kanazawa University, Kanazawa 920-1192, Japan; Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan.

PMID: 18969792
DOI: 10.1016/j.talanta.2004.06.015

Abstract

Possible use of room temperature ionic liquids (RTILs) as chelate extraction solvent was evaluated by using 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF(6)]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([hmim][PF(6)]) and 1-octyl-3-methylimidazolium hexafluorophosphate ([omim][PF(6)]). These RTILs showed high extraction performance for divalent metal cations with 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (Htta). The extracted metals were back-extracted into 1moldm(-3) nitric acid quantitatively. Furthermore, the extracted species were estimated as neutral hydrated complexes M(tta)(2)(H(2)O)(n) (n= 1 or 2) for M = Ni, Cu and Pb and anionic complexes M(tta)(3)(-) for M = Mn, Co, Zn and Cd.