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Org Lett. 2008 Nov 6;10(21):4739-42. doi: 10.1021/ol801780c. Epub 2008 Sep 18.

Two-step synthesis of the immunogenic bacterial glycolipid BbGL1.

Author information

1
University of California, Davis, Department of Chemistry, One Shields Avenue, Davis, California 95616, USA.

Abstract

Chemical synthesis of a bacterial glycolipid BbGL1 is reported in two steps starting from per-O-TMS D-galactose. The key features are glycosyl iodide mediated beta-stereoselective glycosylation in the absence of neighboring group participation and regioselective acylation.

PMID:
18798644
PMCID:
PMC4492534
DOI:
10.1021/ol801780c
[Indexed for MEDLINE]
Free PMC Article

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