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Org Lett. 2008 Sep 4;10(17):3737-9. doi: 10.1021/ol801375k. Epub 2008 Aug 5.

Total synthesis of a marine alkaloid from the tunicate Dendrodoa grossularia.

Author information

1
Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.

Abstract

A short synthesis of an indole marine alkaloid (1) from the tunicate Dendrodoa grossularia is described. The key step in the synthesis involves a novel twist on an underutilized oxazole rearrangement, which produces the quaternary stereocenter in the molecule.

PMID:
18680306
DOI:
10.1021/ol801375k
[Indexed for MEDLINE]

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