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Org Lett. 2008 Sep 4;10(17):3741-4. doi: 10.1021/ol801390h. Epub 2008 Jul 31.

A new pH-switchable dimannosyl[c2]daisy chain molecular machine.

Author information

1
Institut des Biomolécules Max Mousseron, UMR 5247CNRS-Universités Montpellier 2 et 1, Bâtiment de Recherche Max Mousseron, Ecole Nationale Supérieure de Chimie de Montpellier, 34296 Montpellier Cedex 5, France. frederic.coutrot@univ-montp2.fr

Abstract

The preparation of a dimannosyl[c2]daisy chain molecular machine containing an ammonium and a triazolium station is described. The both stretched and contracted states of the molecular machine can be obtained by variation of the pH, thus localizing the mannosyl stoppers closer or farther away.

PMID:
18666774
DOI:
10.1021/ol801390h
[Indexed for MEDLINE]

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