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Phys Rev Lett. 2008 Jun 13;100(23):238301. Epub 2008 Jun 9.

Experimental verification of morphological instability in freezing aqueous colloidal suspensions.

Author information

1
Department of Geology and Geophysics, Yale University, New Haven, CT 06520, USA.

Abstract

We describe an experimental test of a new theory of the unidirectional freezing of aqueous colloidal suspensions. At low freezing speeds a planar ice lens completely rejects the particles, forming a steady-state compacted boundary layer in the liquid region. At higher speeds the planar interface becomes thermodynamically unstable and breaks down geometrically to trap bulk regions of colloid within. The theoretical stability threshold is determined experimentally, thereby demonstrating that colloidal suspensions can be treated analogously to atomic or molecular alloys.

PMID:
18643549
DOI:
10.1103/PhysRevLett.100.238301
[Indexed for MEDLINE]

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