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Inorg Chem. 2008 Sep 1;47(17):7444-6. doi: 10.1021/ic8009145. Epub 2008 Jul 11.

Biphasic hydrogenation over PVP stabilized Rh nanoparticles in hydroxyl functionalized ionic liquids.

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1
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.

Abstract

Polyvinyl pyrrolidone stabilized rhodium nanoparticles are highly soluble in hydroxyl-functionalized ionic liquids, providing an effective and highly stable catalytic system. In hydrogenation reactions, excellent results were obtained, and transmission electron microscopy, solubility determinations, and leaching experiments were employed to quantify the advantages of this catalytic system.

PMID:
18616239
DOI:
10.1021/ic8009145
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