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Chemistry. 2008;14(31):9468-80. doi: 10.1002/chem.200800697.

Solid-phase synthesis of transition-metal complexes.

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1
Department of Inorganic Chemistry, University of Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg (Germany). katja.heinze@urz.uni-heidelberg.de

Abstract

This overview highlights recent progress in the field of selective construction of linear, oligonuclear transition-metal complexes by using solid-phase synthesis procedures. Two general protocols have been identified: formation of coordinative bonds between metal centres and bridging ligands and formation of covalent bonds between preformed kinetically inert transition-metal-containing building blocks in the chain growth step. Currently available suitable building blocks for the second approach are based on ferrocene units, bis(terpyridine)-ruthenium(II) moieties or metal porphyrins.

PMID:
18613162
DOI:
10.1002/chem.200800697
[Indexed for MEDLINE]
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