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J Am Chem Soc. 2008 Jul 2;130(26):8136-7. doi: 10.1021/ja803154h. Epub 2008 Jun 10.

Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions.

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1
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, Liaoning 116023, PR China.

Abstract

Efficient rhodium(I)-catalyzed regioselective functionalization of aromatic C-H bonds has been realized with acid chlorides as the coupling partners via decarbonylation and C-H activation under phosphine-free conditions.

PMID:
18540607
DOI:
10.1021/ja803154h
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