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Chem Commun (Camb). 2008 Jun 14;(22):2562-4. doi: 10.1039/b804405h. Epub 2008 May 2.

Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex.

Author information

1
Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, CNRS-Université Lyon, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France. alexander.sorokin@ircelyon.univ-lyon1.fr

Abstract

A stable mu-nitrido diiron phthalocyanine activates H2O2 to oxidize CH4 in water at 25-60 degrees C to methanol, formaldehyde and formic acid as evidenced using 13C and 18O labelling.

PMID:
18506244
DOI:
10.1039/b804405h
[Indexed for MEDLINE]
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