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Langmuir. 2008 Jun 17;24(12):6262-9. doi: 10.1021/la8003504. Epub 2008 May 15.

Dynamic effects of bouncing water droplets on superhydrophobic surfaces.

Author information

1
Nanotribology Laboratory for Information Storage and MEMS/NEMS, The Ohio State University, 201 West 19th Avenue, Columbus, Ohio 43210-1142, USA.

Abstract

Superhydrophobic surfaces have considerable technological potential for various applications due to their extreme water repellent properties. Superhydrophobic surfaces may be generated by the use of hydrophobic coating, roughness, and air pockets between solid and liquid. Dynamic effects, such as the bouncing of a droplet, can destroy the composite solid-air-liquid interface. The relationship between the impact velocity of a droplet and the geometric parameters affects the transition from the solid-air-liquid interface to the solid-liquid interface. Therefore, it is necessary to study the dynamic effect of droplets under various impact velocities. We studied the dynamic impact behavior of water droplets on micropatterned silicon surfaces with pillars of two different diameters and heights and with varying pitch values. A criterion for the transition from the Cassie and Baxter regime to the Wenzel regime based on the relationship between the impact velocity and the parameter of patterned surfaces is proposed. The trends are explained based on the experimental data and the proposed transition criterion. For comparison, the dynamic impact behavior of water droplets on nanopatterned surfaces was investigated. The wetting behavior under various impact velocities on multiwalled nanotube arrays also was investigated. The physics of wetting phenomena for bouncing water droplet studies here is of fundamental importance in the geometrical design of superhydrophobic surfaces.

PMID:
18479153
DOI:
10.1021/la8003504

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