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Org Lett. 2008 Jun 5;10(11):2311-3. doi: 10.1021/ol800733b. Epub 2008 May 8.

Mn-mediated coupling of alkyl iodides and ketimines: a radical addition route to alpha,alpha-disubstituted alpha-aminoesters.

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1
Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA. gregory-friestad@uiowa.edu

Abstract

Coupling of primary and secondary alkyl iodides with N-acylhydrazonoesters via Mn-mediated photolysis conditions affords access to tert-alkyl amines.

PMID:
18461956
DOI:
10.1021/ol800733b
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