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J Am Chem Soc. 2008 May 28;130(21):6734-6. doi: 10.1021/ja8018675. Epub 2008 May 6.

Poly(3,4-ethylenedioxyselenophene).

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1
Department of Organic Chemistry and Chemical Research Support Unit, Weizmann Institute of Science, Rehovot 76100, Israel.

Abstract

The first highly conductive polyselenophene, namely, poly(3,4-ethylenedioxyselenophene) (PEDOS), was synthesized by taking advantage of a novel method for efficiently contracting the selenophene ring. PEDOS shows a relatively low band gap (1.4 eV), very high stability in the oxidized state, and a well-defined spectroelectrochemistry.

PMID:
18457395
DOI:
10.1021/ja8018675
[Indexed for MEDLINE]
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