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Inorg Chem. 2008 May 5;47(9):3495-7. doi: 10.1021/ic800195u. Epub 2008 Apr 8.

Three-dimensional homochiral transition-metal camphorate architectures directed by a flexible auxiliary ligand.

Author information

1
Department of Chemistry and Biochemistry, California State University-Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.

Abstract

Reported here are four homochiral and one racemic chiral compounds assembled from transition metals (Fe2+, Co2+, and Ni2+), rigid enantiopure camphoric acid, and flexible 4,4'-trimethylenedipyridine; they feature an unusual homochiral three-dimensional supramolecular assembly (resulting from catenation of 4-connected bilayers) as well as a homochiral 3-fold interpenetrating diamond net and a noninterpenetrating primitive cubic net.

PMID:
18393493
DOI:
10.1021/ic800195u
[Indexed for MEDLINE]

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