Format

Send to

Choose Destination
See comment in PubMed Commons below
Chem Commun (Camb). 2008 Apr 21;(15):1744-6. doi: 10.1039/b717571j. Epub 2008 Feb 6.

An unusually stable octanuclear sigma-mesityl-bridged mu4-oxo-copper(I) complex encapsulated by a pyrazolate-based compartmental ligand scaffold.

Author information

  • 1Institut für Anorganische Chemie, Georg-August-Universität, Tammannstrasse 4, D-37077 Göttingen, Germany.

Abstract

A new compartmental pyrazole-derived chelating ligand, four equivalents of mesitylcopper and stoichiometric amounts of dioxygen lead to the formation of a remarkably stable organometallic framework that can be described as a heteroleptic O-centered cuprate anion [(MesCu(I))(4)(mu(4)-O)](2-) linked via sigma-mesityl-bridges to two surrounding binuclear Cu(I)-pyrazolate clamps.

PMID:
18379679
DOI:
10.1039/b717571j
[PubMed]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for Royal Society of Chemistry
    Loading ...
    Support Center