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J Am Chem Soc. 2008 Apr 23;130(16):5406-7. doi: 10.1021/ja800656y. Epub 2008 Mar 26.

Localized Pd overgrowth on cubic Pt nanocrystals for enhanced electrocatalytic oxidation of formic acid.

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1
Department of Chemical Engineering, Yonsei University, Seoul, South Korea.

Abstract

Binary Pt/Pd nanoparticles were synthesized by localized overgrowth of Pd on cubic Pt seeds for the investigation of electrocatalytic formic acid oxidation. The binary particles exhibited much less self-poisoning and a lower activation energy relative to Pt nanocubes, consistent with the single crystal study.

PMID:
18366165
DOI:
10.1021/ja800656y

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