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Molecules. 2004 Jan 31;9(1):22-8.

Addition of organochromium reagents to heteroaryl aldehydes. Synthesis of heteroaryl substituted bis-allyl ethers and homoallyl ethers.

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1
Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey. sservi@firat.edu.tr

Abstract

Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.

PMID:
18007408
[Indexed for MEDLINE]
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