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Chem Commun (Camb). 2007 Dec 7;(45):4746-8. Epub 2007 Sep 6.

A new functionalization strategy for pentacene.

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1
Department of Chemistry, University of Kentucky, Lexington, KY 40506-0055, USA. anthony@uky.edu

Abstract

Functionalization of the pro-cata positions of pentacene with groups held perpendicular to the aromatic plane, in this case through a rigid 1,3-dioxole unit, yields pentacene derivatives that are stable and soluble, and still maintain edge-to-face interactions in the solid state.

PMID:
18004428
DOI:
10.1039/b711296c
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