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J Chromatogr A. 2008 Apr 4;1186(1-2):109-22. Epub 2007 Oct 18.

Developments in the application of gas chromatography with atomic emission (plus mass spectrometric) detection.

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1
Free University, Department of Analytical Chemistry and Applied Spectroscopy, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands. leo.vanstee@tno.nl

Abstract

Capillary gas chromatography with atomic emission detection is a highly element-selective and sensitive detection technique for many non-metal as well as metallic elements. A 3-5 order of magnitude element/carbon selectivity, compound-independent calibration and the possibility to calculate (partial) molecular formulae are some of the attractive features of the technique. In the present review, the emphasis is on real-life applications for non-metals such as sulphur, phosphorus, nitrogen and the halogens, and on the potential of combined atomic emission/mass spectrometric detection.

PMID:
18001754
DOI:
10.1016/j.chroma.2007.10.031
[Indexed for MEDLINE]
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