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Org Lett. 2007 Sep 27;9(20):4053-6. Epub 2007 Sep 1.

Chlorofluorocarbene: first UV observation of a dihalocarbene in solution.

Author information

  • 1Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu

Abstract

Chlorofluorocarbene (ClCF), generated by laser flash photolysis of chlorofluorodiazirine, absorbs at 368 nm in pentane. Absolute rate constants are reported for ClCF additions to several alkenes and pyridine. ClCF is less reactive toward alkenes than CCl(2), and it does not react rapidly with oxygen. Pertinent computational studies are included.

PMID:
17764197
DOI:
10.1021/ol701804m
[PubMed]
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