High-yielding one-pot synthesis of diaryliodonium triflates from arenes and iodine or aryl iodides

Marcin Bielawski; Berit Olofsson

doi:10.1039/b701864a

High-yielding one-pot synthesis of diaryliodonium triflates from arenes and iodine or aryl iodides

Chem Commun (Camb). 2007 Jun 28:(24):2521-3. doi: 10.1039/b701864a. Epub 2007 Mar 20.

Authors

Marcin Bielawski¹, Berit Olofsson

Affiliation

¹ Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.

PMID: 17563816
DOI: 10.1039/b701864a

Abstract

Unsymmetric and symmetric diaryliodonium triflates are synthesized from both electron-deficient and electron-rich substrates in a fast, high yielding, and operationally simple protocol employing arenes and aryl iodides or iodine.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Biphenyl Compounds / chemical synthesis*
Biphenyl Compounds / chemistry
Hydrocarbons, Iodinated / chemical synthesis*
Hydrocarbons, Iodinated / chemistry
Iodine / chemistry*
Mesylates / chemistry*
Molecular Structure
Onium Compounds / chemical synthesis*
Onium Compounds / chemistry

Substances

Biphenyl Compounds
Hydrocarbons, Iodinated
Mesylates
Onium Compounds
diphenyliodonium
Iodine
trifluoromethanesulfonic acid