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Nano Lett. 2007 Jun;7(6):1622-5. Epub 2007 May 18.

Transition of single-walled carbon nanotubes from metallic to semiconducting in field-effect transistors by hydrogen plasma treatment.

Author information

1
Department of Physics and Tsinghua-Foxconn Nanotechnology Research Centre, Tsinghua University, Beijing 100084, People's Republic of China.

Abstract

We report hydrogen plasma treatment results on converting the metallic single-walled carbon nanotubes to semiconducting single-walled carbon nanotubes. We found that the as-grown single-walled carbon nanotubes (SWNTs) can be sorted as three groups which behave as metallic, as-metallic, and semiconducting SWNTs. These three groups have different changes under hydrogen plasma treatment and successive annealing process. The SWNTs can be easily hydrogenated in the hydrogen plasma environment and the as-metallic SWNTs can be transformed to semiconducting SWNTs. The successive annealing process can break the C-H bond, so the conversion is reversible.

PMID:
17508771
DOI:
10.1021/nl070585w
[Indexed for MEDLINE]

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