This paper reports the application of fuzzy set theory for decision-making in the assessment of physico-chemical quality of groundwater for drinking purposes. Methodology based on fuzzy set theory used to express the quality of water in the imprecise environment of monitored data and prescribed limits given in a non-probabilistic sense. Fuzzy synthetic evaluation model gives the certainty levels for the acceptability of the water based on the prescribed limit of various regulatory bodies quality class and perception of the experts from the field of drinking water quality. Application of fuzzy rule based optimization model is illustrated with 42 groundwater samples collected from the 15 villages of Ateli block of southern Haryana, India. These samples were analysed for 16 different physico-chemical water quality parameters. Ten parameters were used for the quality assessment using this approach. The analysis showed that four samples were in "desirable" category with certainty level of 35-58%, 23 samples were in "acceptable" category whose certainty level ranged from 37 to 75% and remaining 15 samples were in "not acceptable" category for drinking purposes with certainty levels from 44 to 100%. This concludes that about 64% water sources were either in "desirable" or "acceptable" category for drinking purposes.