Encapsulation of a (H3O2)- unit in the aromatic core of a calix[6]arene closed by two Zn(II) ions at the small and large rims

Chem Commun (Camb). 2006 Oct 1:(37):3924-6. doi: 10.1039/b608203c. Epub 2006 Aug 4.

Abstract

The coordination of a first Zn(II) ion to a calix[6]arene presenting three imidazolyl arms at the small rim and three aniline moieties at the large rim allows the binding of a second Zn(II) ion while hosting a (H3O2)- unit in the aromatic cavity.

MeSH terms

  • Aniline Compounds / chemistry
  • Calixarenes / chemical synthesis*
  • Cations, Divalent
  • Hydroxides / chemistry*
  • Imidazoles / chemistry
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Phenols / chemical synthesis*
  • Zinc / chemistry*

Substances

  • Aniline Compounds
  • Cations, Divalent
  • Hydroxides
  • Imidazoles
  • Organometallic Compounds
  • Phenols
  • calix(6)arene
  • Calixarenes
  • imidazole
  • Zinc
  • aniline