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Chem Commun (Camb). 2007 Feb 14;(6):571-3. Epub 2006 Nov 15.

Experimental and theoretical evidence of the first Au(i)...Bi(iii) interaction.

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1
Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC. Complejo Científico-Tecnológico, 26004, Logroño, Spain. eduardo.fernandez@dq.unirioja.es

Abstract

Complex [Au(C6F5)2][Bi(C6H4CH2NMe(2)-2)2] displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).

PMID:
17264894
DOI:
10.1039/b613365g
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