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Org Lett. 2007 Jan 4;9(1):109-11.

Ligand-promoted dehydrogenation of alcohols catalyzed by Cp*Ir complexes. A new catalytic system for oxidant-free oxidation of alcohols.

Author information

  • 1Graduate School of Human and Environmental Studies, and Graduate School of Global Environmental Studies, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan. fujitak@kagaku.mbox.media.kyoto-u.ac.jp

Abstract

[reaction: see text] An efficient catalytic system for oxidant-free oxidation of alcohols has been developed. A new Cp*Ir catalyst bearing a 2-hydroxypyridine ligand has been designed on the concept of "ligand-promoted dehydrogenation". Various secondary alcohols can be dehydrogenatively oxidized to ketones under neutral conditions with high turnover numbers by using the new Cp*Ir catalyst.

PMID:
17192097
DOI:
10.1021/ol062806v
[PubMed - indexed for MEDLINE]
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