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Chem Commun (Camb). 2006 Sep 14;(34):3591-3. Epub 2006 Aug 7.

Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid.

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1
Liverpool Center for Materials and Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UK L69 7ZD.

Abstract

In contrast to almost all of the known examples of Heck arylation of unsaturated alcohols, which yield predominately beta-arylated products, arylation under the Pd-DPPP catalysis in ionic liquid leads preferentially to aryl substitution at the alpha carbon, providing an easy pathway to this valuable class of olefins.

PMID:
17047774
DOI:
10.1039/b608033b
[Indexed for MEDLINE]
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