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J Org Chem. 2006 Sep 29;71(20):7874-6.

Copper-catalyzed 1,2-hydroxysulfenylation of alkene using disulfide via cleavage of the S-S bond.

Author information

1
Department of Chemistry, Fukushima Medical University, Fukushima 960-1295, Japan. taniguti@fmu.ac.jp

Abstract

Copper-catalyzed 1,2-hydroxysulfenylation of alkenes can be carried out by the use of disulfides and acetic acid in air. This reaction regio- and anti-selectively gave the corresponding 1,2-acetoxysulfides. Furthermore, the present method enables the use of both organosulfide groups of disulfide.

PMID:
16995702
DOI:
10.1021/jo060834l

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