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J Am Chem Soc. 2006 Aug 9;128(31):10030-1.

Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution: a sharp phase transition at the lower critical solution temperature.

Author information

1
Department of Macromolecular Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

Abstract

The number of hydrated water molecules per poly(N-isopropylacrylamide) monomer unit in homogeneous aqueous solution was determined to be 11 exactly and anew below the lower critical solution temperature of 32 degrees C employing high-frequency dielectric relaxation techniques.

PMID:
16881629
DOI:
10.1021/ja063990i

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