Molecular dynamics (MD) simulations were performed on N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide (mppy+TFSI-) from 303 to 393 K to improve understanding of the structure and ion transport of this ionic liquid. The density, ion self-diffusion coefficients, conductivity, and viscosity of mppy+TFSI- predicted from MD simulations are in good agreement with experimental measurements. The time-dependent shear modulus of the ionic liquids was calculated and compared with that for nonionic liquids. On average each mppy+ cation was found to be coordinated by four TFSI- anions. The angular distributions of N(TFSI-)-N(mppy+)-N(TFSI-) and N(mppy+)-N(TFSI-)-N(mppy+) exhibit a maximum at 80-90 degrees and a second maximum at 180 degrees . Correlation of ion motion was found to lower ionic conductivity by approximately one-third from the expected value based upon ion self-diffusion coefficients. Rotational motion of the cation and anion are anisotropic with the degree of anisotropy increasing with decreasing temperature. Electrostatic interactions are responsible for slowing down the dynamics of the ionic liquid by more than an order of magnitude and a dramatic decrease of the time-dependent shear modulus.