Dynamics of capillary condensation in aerogels

Phys Rev E Stat Nonlin Soft Matter Phys. 2006 Mar;73(3 Pt 1):032601. doi: 10.1103/PhysRevE.73.032601. Epub 2006 Mar 8.

Abstract

Dynamics of capillary condensation of liquid 4He in various density silica aerogels was investigated systematically. Interfaces were clearly visible when bulk liquid was rapidly sucked into the aerogel. Time evolution of the interface positions was consistent with the Washburn model and their effective pore radii were obtained. Condensation was a single step in a dense aerogel and two steps in a low density aerogel. Crossover between the two types of condensation was observed in an intermediate density aerogel. Variety of the dynamics may be the manifestation of the fractal nature of aerogels which had a wide range of distribution of pore radii.