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Org Lett. 2006 Mar 16;8(6):1141-4.

Oxone as an inexpensive, safe, and environmentally benign oxidant for C-H bond oxygenation.

Author information

1
University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA.

Abstract

[reaction: see text] This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.

PMID:
16524288
DOI:
10.1021/ol0530272
[Indexed for MEDLINE]

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