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Dalton Trans. 2006 Mar 14;(10):1267-70. Epub 2006 Jan 10.

Substituent dependence of the reactions of [RuCl2(PPh3)3] with bulky aromatic thiols.

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1
Johnson-Matthey Technology Centre, Blounts Court, Sonning Common, Reading, RG4 9NH, UK.

Abstract

2,4,6-trialkylbenzenethiols react with [RuCl2(PPh3)3] to give Ru products with the alkyl substituents forming M-C sigma bonds, carbene, carbene with a S alpha-heteroatom, agostic hydrogen interaction or a simple tetrahedral Ru(II) species, depending on the substituent.

PMID:
16505904
DOI:
10.1039/b515244e
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