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J Am Chem Soc. 2006 Jan 11;128(1):8-9.

Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes.

Author information

1
Department of Chemistry, Stanford University, Stanford, CA 94305-8080, USA. bmtrost@stanford.edu

Abstract

Our recent development of a proline-derived bimetallic catalyst has led to a number of efficient, catalytic, enantioselective transformations. Herein, we report a practical and general alkynylation of aromatic and alpha,beta-unsaturated aldehydes using our zinc catalyst system.

PMID:
16390095
PMCID:
PMC2596613
DOI:
10.1021/ja054871q
[Indexed for MEDLINE]
Free PMC Article

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