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J Am Chem Soc. 2005 Dec 28;127(51):18022-3.

The chlorate-iodine clock reaction.

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1
Instituto de QuĂ­mica, Universidade Federal do Rio de Janeiro, Caixa Postal 68563, Rio de Janeiro, RJ, 21945-970 Brazil.

Erratum in

  • J Am Chem Soc. 2007 Jul 11;129(27):8668.

Abstract

A clock reaction produced by mixing chlorate and iodine solutions in perchloric acid media is reported. This is the first example of a clock reaction using chlorate as a reagent. Increasing chlorate and acid concentration reduces the induction period. Changing the initial iodine concentration does not affect the length of the induction period. The discovery of this clock reaction opens the possibility that a new family of oscillation reactions can be built using chlorate as reagent.

PMID:
16366551
DOI:
10.1021/ja0570537
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