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Chem Commun (Camb). 2005 Dec 14;(46):5787-9. Epub 2005 Oct 20.

A novel sheet 4f-3d mixed-metal pyridine dicarboxylate: synthesis, structure, photophysical properties and its transformation to a perovskite oxide.

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1
Framework Solids Laboratory, Solid State Structural Chemistry Unit, Indian Institute of Science, Bangalore.

Abstract

The synthesis, characterization and photophysical properties of a 4f-3d mixed metal compound, Gd(H2O)3Co[C5N1H3(COO)2]3, are described; the structure is unique, consisting of sheets with large pores (ca. 7 Angstroms diameter) in the sheets and transforms to a perovskite oxide at moderate temperatures.

PMID:
16307146
DOI:
10.1039/b509588c
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