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J Am Chem Soc. 2005 Oct 19;127(41):14162-3.

Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer.

Author information

1
State Key Laboratory of Photoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.

Abstract

Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer [Ag6Cl(atz)4].OH.6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption.

PMID:
16218592
DOI:
10.1021/ja054913a
[Indexed for MEDLINE]

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