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J Am Chem Soc. 2005 Oct 12;127(40):13744-5.

Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111).

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1
Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, D-44870 Bochum, Germany.

Abstract

Metal-Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.

PMID:
16201767
DOI:
10.1021/ja053523l
[Indexed for MEDLINE]
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